There are two system SMTP relays you can choose for each individual mail server - POP before SMTP and SMTP AUTH.
In POP before SMTP, the relay system collects IP addresses of users who successfully authenticate themselves with a POP server, and then permits SMTP relaying from that IP address for a short period of time.
If clients do not have known IP addresses, relays use SMTP AUTH, an SMTP based protocol, in which the client must send a name and password in addition to the normal SMTP envelope information. Obviously this requires a special client, which has been configured to use this protocol.
To specify the protocol for a specific server:

